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This portion of the Cyberpunk 2077 guide explains how to use photomode.
Photomode is never explicitly discussed in the game but it's a robust featured filled with fun poses (Easter Eggs) and plenty of options. Here's how to use photomode.
As you might expect, using photo mode only centers around your chosen character - but there is away to snap some great pictures of a certain silver-handed fellow.
During certain scenes in the main story you will essentially relive a memory as Johnny Silverhand. While most of your options are limited during these memories, you can in fact still use photo mode to take pictures playing as the other character.